LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:THE PRINCIPAL VOLATILE COMPONENT IS
WATER. MINOR VOLATILE COMPONENTS ARE FORMALDEHYDE & VINYL ACETATE.
BOTH MINOR COMPONENTS WILL MIGRATE FROM EMULSION & ESTABLISH AN
EQUILIBRIUM CNDTN BETWEEN HEADSPA CE IN THE STORAGE CNTNR & LIQ
EMULSION.LEVS IN EXCESS OF TLV'S (2PPM FOR FORMALDEHYDE, 10PPM FOR
VINYL(EFTS OF OVEREXP)
Explanation of Carcinogenicity:FORMALDEHYDE: GROUP 2A (IARC); GROUP 2
(NTP); OSHA REGULATED.
Effects of Overexposure:HLTH HAZ: ACETATE) CAN ACCUMULATE IN NON-VENTED
HEADSPACES ABOVE STORED EMULSION. CARE MUST BE EXERCISED TO VENT
HEADSPACE OF STORAGE TANKS W/HUMIDIFIED AIR. DRUMS SHOULD BE OPENED
IN WELL VENT SPACE. FORMALDEHYDE CONC IN THE WORK PLACE MAYEXCEED
TLV UNDER SOME CNDNTS OF USE. ALTHOUGH FORMALDEHYDE IS A MINOR(SUPP
DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN: WASH WITH SOAP AND WATER. EYE: IF SPLASHED IN EYE,
FLUSH WITH COPIOUS QUANTITIES OF WATER FOR AT LEAST 15 MINUTES AND
SEEK MEDICAL ADVICE. INGEST: INGEST AMTS ARE NOT ANTICIPATED TO
PRODUCE ADVE RSE HLTH EFTS, BUT SHOULD BE REMOVED FROM STOMACH BY
INDUCED VOMIT/ASPIR. CALL MD. INHAL: REMOVE TO FRESH AIR. SUPPORT
BREATHING (GIVE O*2/ARTF RESP) .

Extinguishing Media:FOR DRY POLYMER, USE WATER OR CO*2.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
.WHEN POLYMER BURNS, WATER, CO*2, CO & SMOKE ARE PRODUCED.
PYROLYSIS PRODS MAY INCL SUCH MATL (SUPP DATA)
Unusual Fire/Explosion Hazard:THERE ARE NO UNUSUAL FIRE OR EXPLOSION
HAZARDS.

Spill Release Procedures:IF MATL IS RELS/SPILL, DAM UP TO LIM
SPREAD.MOP UP/ABSORB ON INERT MATL & PLACE IN CNTNRS.IF SPILL
OCCURS IN ENCLSD AREA, VENT.POLYMER MAY BE SEPARATED FROM WATER BY
ADDTN OF ALUM & FERRIC CHLORIDE.FO R FURTHER SPILL PROC REFER TO
ORIGINAL MSDS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A COOL PLACE, AVOID FREEZING.
MINIMIZE CONT W/AIR TO PVNT INNOCULATION W/MICROORGANISMS WHICH CAN
CAUSE DECOMP & MOLDY OVERGROWTH.
Other Precautions:THE PROD WILL IMPART A WHITE MILKY COLOR TO WATER.
WHEN WATER IS AGITATED/IS TURBULENT, FOAMING CAN RESULT. AS
SUPPLIED/DILUTED, PROD MATL (FOAM INCL) WHEN SPLASHED ON AUTOS OR
OTHER PERSONAL PROPERTY IS DIFFICULT TO REMOVE IF ALLOWED DRY.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:IF HEADSPACE VENT IS REQUIRED, USE HUMIDIFIED AIR TO REDUCE
SKIN FORMATION ON THE EMULSION SURFACE.
Protective Gloves:RUBBER PROTECTIVE GLOVES ARE REQUIRED.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NORMAL CLEANLINESS SHOULD BE OBSERVED.
Supplemental Safety and Health
FIRE FIGHT PROC:AS ACETIC ACID, ACROLEIN/ACETALDEHYDE. MASKS TO REMOVE
SMOKE & ORG VAP FROM RESP AIR ARE RECOMMENDED FOR USE WHEN FIGHTING
FIRES INVOLVING VINYL ACETATE POLYMERS & COPOLYMERS. EFTS OF
OVEREXP:VOLATILE COMPONENT OF THESE EMULSION PRODS, IT IS IMPORTANT
TO RECOGNIZE THAT RECENT TEST RESULTS HAVE (ING 8)

HCC:T6
Solubility in Water:WATER MISCIBLE
Appearance and Odor:WHITE, MOBILE LIQUID, WITH A PLEASANT, SWEET ODOR.

Stability Indicator/Materials to Avoid:YES
SULFURIC ACID OR ALKALI MATERIALS SUCH AS SODIUM OR METAL HYDRIDES.
Stability Condition to Avoid:COAGULATION MAY OCCUR FOLLOWING FREEZING,
THAWING OR BOILING.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Methods:FOR SM SPILLS (PROBABLY LESS THAN 100 GALLONS),
DILUTE W/WATER. WASH INTO INDUSTRIAL SEWER. (WARNING, CONSULT LOCAL
SEWER AUTHORITY BEFORE DISCHARGING). FOR LRG QTYS, PLACE IN
SETTLING POND & ADD FERR IC CHLORIDE & LIME. DECANT WATER. (ING 5)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.